CHEMISTRY OF ADVANCED MATERIALS AN OVERVIEWPDF电子书下载

1. Introductory Terms and Concepts&Mark J.Hampden-Smith and Leonard V.Interrante 1

1.1 Materials Chemistry：Introduction 1

1.2 Materials Chemistry：Past 2

1.3 Materials Chemistry：Present 5

1.4 Materials Chemistry：Future 14

References 17

General Bibliography 18

2. Electron-Transfer Salt-Based Conductors，Superconductors，and Magnets&Patrick Cassoux and Joel S.Miller 19

2.1 Introduction 19

2.2 Definitions and Units 21

2.3 Historical Background 25

2.4 One-Dimensional Conductors 27

2.5 Quasi One- and Two-Dimensional Superconductors 31

2.6 Fullerides 40

2.7 Related Research Areas 42

2.8 Electron-Transfer Salt-Based Magnets 47

2.9 Conclusions 57

References 59

3. Advanced Polymeric Materials：Functional Electroactive Polymers&Bashir M.Sheikh-Ali and Gary E.Wnek 73

3.1 Introduction 73

3.2 Brief Structural Overview of Conjugated Polymers 73

3.3 Synthesis， Processing， and Doping of Conjugated Polymers 74

3.4 Ionically Conducting Polymers 80

3.5 Applications of Conjugated Polymers 83

3.6 Electronically and Ionically Conducting Polymers in Energy Storage Applications 89

3.7 Other Electroactive Polymer Systems 92

References 93

4. Polymers in Electronics&E.Reichmanis and T.X.Neenan 99

4.1 Introduction 99

4.2 Lithographic Materials 100

4.3 Resist Design Requirements 102

4.4 Solution-Developed Resist Chemistry 103

4.5 Dry-Developed Resist Chemistry 117

4.6 Polymers as Packaging Materials and Encapsulants 121

References 131

5. Chemical Vapor Deposition&Mark J.Hampden-Smith，Toivo T.Kodas，and Audunn Ludviksson 143

5.1 Introduction 143

5.2 Fundamental Aspects of CVD Processes 150

5.3 Overview of Vapor-Phase Deposition Methods， Related and Unrelated to CVD 171

5.4 Case Studies 180

5.5 Summary，Conclusions，and Future Directions 197

References 198

6. Introduction to the Nonlinear Optical Properties of Organic Materials&Fabienne Meyers，Seth R.Marder，and Joseph W.Perry 207

6.1 Introduction 207

6.2 Basic Concepts 208

6.3 Quantum-Chemical Description 219

6.4 Molecular Structure-NLO Properties Relationships 225

6.5 Materials Design 243

6.6 Conclusions 261

References 262

7. Nanoparticles and Nanostructural Materials&Kenneth J.Klabunde and Cathy Mohs 271

7.1 A World Bounded by Chemistry and Solid-State Physics 271

7.2 Methods of Preparation 278

7.3 Physical Properties 293

7.4 Chemical Properties of Surfaces 304

7.5 Possible Applications of Nanoparticles 316

References 318

8. Nanoporous Materials&Peter T.Tanev，Jean-Remi Butruille，and Thomas J.Pinnavaia 329

8.1 Introduction 329

8.2 Zeolites and Molecular Sieves 330

8.3 Porous Lamellar Solids 358

8.4 Summary and Conclusions 379

References 381

9. Molecular Precursor Routes to Inorganic Solids&Jacques Livage，C.Sanchez，and F.Babonneau 389

9.1 Introduction 389

9.2 Sol-Gel Chemistry of Metal Alkoxides 390

9.3 Hybrid Organic-Inorganic Compounds 409

9.4 Polymeric Routes to Nonoxide Ceramics 429

9.5 Conclusions 441

References 442

General Bibliography 445

10. Layered Transition-Metal Oxides and Chalcogenides&Paul A.Salvador，Thomas O.Mason，Michael E.Hagerman，andKenneth Poeppelmeier 449

10.1 Introduction 449

10.2 Materials Chemist’s Approach 455

10.3 Layering in Advanced Materials 469

10.4 Summary and Future Prospects 486

References 491

11. Biomaterials&Carole C.Perry 499

11.1 Introduction 499

11.2 Key Tissues in the Human Body 504

11.3 Biomineralization： The Controlled Formation of Biological Composites 510

11.4 Bone and Other Mineralized Tissues 519

11.5 Materials of Construction 527

11.6 Other Applications 553

11.7 Biocompatibility Testing 555

11.8 Funding for Research：The Way Forward 557

References 558

Index 563