ADVANCED PHYSICO-CHEMICAL EXPERINENTSPDF电子书下载

Ⅰ.ANALYSIS 1

1.The Beer-Lambert Law（including Vierordt’smethod） 3

2.Chronopotentiometric analysis 6

3.“Dead-stop”end-point titrations（amperometric） 13

4.Differential conductimetric titration of very weak bases in aqueous solution 17

5.Differential potentiometric titrations of mixtures of acids 21

6.Estimation of isomers by infra-red absorption 25

7.Lewis acids and bases 29

8.Morton’s spectrophotometric method 32

9.Potentiometric differentiation of alkali metals in mixed solvents 36

10.Qualitative analysis of metals by emissionspectroscopy 39

11.Quantitative spectrochemical trace analysis by the copper-spark method 41

Ⅱ.COMPLEX FORMATION 45

12.Chelating ligands in analysis 47

13.Chelation and pH 51

14.Composition of co-ordination compounds by the method of continuous variation 54

15.Hagenmuller’s modification of the method of continuous variation 59

16.Composition and stability constant of the uranyl-5-sulphosalicylate complex by the limiting logarithmic method 67

17.Polarographic determination of stability con-stants of complex compounds 71

18.Stability constants of co-ordination compounds by Bjerrum’s（potentiometric） method 76

19.Stability constants of co-ordination compounds（Turner-Anderson method） 81

20.Thermodynamics of chelation（effect of metalions） 84

Ⅲ.ELECTROCHEMISTRY 89

21.Activity coefficient of HC1 in aqueous solution 91

22.Activity coefficients and solubilities of sparinglysoluble electrolytes 95

23.Analytical boundary method for transportnumbers 98

24.The Bronsted theory of acids （strengths of inorganic acids in glacial acetic acid） 103

25.Conductimetric titration of mixtures 109

26.The Debye-Hǖckel theory and weak electrolytes 112

27.Ion-association:Bjerrum’s theory（ion-pair and triple-ion formation） 115

28.Ionic product for water(Kw)by the e.m.f.method 121

29.The Onsager equation and its modifications 124

30.Potentiometry at constant intensity 128

31.Thermodynamic ionization constants of weakelectrolytes 133

32.Thermodynamic transfer quantities by e.m.f.measurements 136

33.“Zwitterions” 140

Ⅳ.KINETICS 147

34.Catalytic decomposition of hydrogen peroxide 149

35.Conductimetric study of the kinetics of hydrolysis of tertiary butyl iodide 153

36.Decomposition of ammonia on a tungstensurface 158

37.Dilatometric study of reaction kinetics 162

38.Energies and entropies of activation of isomericrearrangements 166

39.Isomerization equilibrium and kinetics in aqueous solution 172

40.Method of ratio variation 176

41.Primary salt effect 179

42.Secondary salt effect 185

43.Spectroscopic study of the alcoholysis of cinnamal chloride 190

44.Stirred-flow reactor 193

Ⅴ.PHOTOCHRMISTRY 197

45.Photobromination of cinnamic acid（chainreaction） 199

46.Photocatalysis:the photolysis of uranyl oxalate（uranyl-oxalate aotinometer） 203

47.Photochemical dimerization of anthraoene（photo-stationary state） 207

48.Photohydrolysis of monochloroacetic acid（quan-tum efficiency） 213

49.Photosensitization of chemical reactions（the Eder reaction） 218

50.The oxidation of ferrous iron by iodine under the action of ultra-violet radiation 221

Ⅵ.SPECTROSCOPY 225

51.Deviations from the Beer-Lambert Law 227

52.Indicator constants by spectrophotometry 233

53.Infra-red spectra and chemical properties of molecules 236

54.Ion-association by spectrophotometry 240

55.Isobiestic point 245

56.Moment of inertia, internuclear distance, and bond strength of HI by infra-red spectra 250

57.Quenching of fluorescence 257

58.Spectrophotometric determination of molecularweights 264

59.Spectroscopic determination of equilibrium con-stants of molecular compounds （charge-transfer spectra） 267

60.Spectroscopic study of the dimerization of ethanol in non-polar solvents 270

Ⅶ. THERMODYNAMICS 275

61.Activities of electrolytic solutes by the freezing-point method 277

62.Activities from vapour-pressure data 281

63.Activity of thallium in amalgams at 25℃ 286

64.Partial molal volumes 291

65.Partial molal volumes in regular solutions 296

66.Solubility of naphthalene in various solvents（ideal and non-ideal solutions） 299

67.Thermal dissociation of ferric bromide 304

68.Thermodynamic functions of the reaction be-tween malonic acid and some lanthanons 308

69.Thermodynamics of vaporization of liquids 314

Ⅷ.VARIOUS 319

70.Azeotropie distillation（determination of water content） 321

71.Dipole moment of 1:8-dichloronaphthalene by Guggenheim’s method 326

72.Donnan equilibria 329

73.Enthalpy titrations 334

74.The Hammett indicator acidity function H 340

75.Liquid-liquid adsorption of soluble fatty acids（Gibbs’ and Szyszkowski’s equations） 347

76.Magnetic susceptibility （by the Gouy method） 353

77.Molecular weight determination by “isothermic distillation” （Barger’s opposed twin capillary method） 357

78.The reciprocal salt effect and the Janecke projec-tion （phase rule study） 361

79.The ternary diagram by the wet-residue method（phase rule study） 368

80.The ternary diagram by the synthetic-complex method （phase rule study） 372

81.Thermal decomposition of solids （Prout-Tomp-kins’equation） 375

82.The determination of surface areas of adsorbents by means of the B.E.T.isotherm （physicaladsorption） 380

Appendix:Erros,mistakes,and deviations.Method of least squares 389

Index 399