ADVANCED PHYSICO-CHEMICAL EXPERINENTSPDF电子书下载
- 电子书积分:14 积分如何计算积分?
- 作 者:
- 出 版 社:SIR ISAAC PITMAN & SONS LTD
- 出版年份:1964
- ISBN:
- 页数:414 页
Ⅰ.ANALYSIS 1
1.The Beer-Lambert Law(including Vierordt’smethod) 3
2.Chronopotentiometric analysis 6
3.“Dead-stop”end-point titrations(amperometric) 13
4.Differential conductimetric titration of very weak bases in aqueous solution 17
5.Differential potentiometric titrations of mixtures of acids 21
6.Estimation of isomers by infra-red absorption 25
7.Lewis acids and bases 29
8.Morton’s spectrophotometric method 32
9.Potentiometric differentiation of alkali metals in mixed solvents 36
10.Qualitative analysis of metals by emissionspectroscopy 39
11.Quantitative spectrochemical trace analysis by the copper-spark method 41
Ⅱ.COMPLEX FORMATION 45
12.Chelating ligands in analysis 47
13.Chelation and pH 51
14.Composition of co-ordination compounds by the method of continuous variation 54
15.Hagenmuller’s modification of the method of continuous variation 59
16.Composition and stability constant of the uranyl-5-sulphosalicylate complex by the limiting logarithmic method 67
17.Polarographic determination of stability con-stants of complex compounds 71
18.Stability constants of co-ordination compounds by Bjerrum’s(potentiometric) method 76
19.Stability constants of co-ordination compounds(Turner-Anderson method) 81
20.Thermodynamics of chelation(effect of metalions) 84
Ⅲ.ELECTROCHEMISTRY 89
21.Activity coefficient of HC1 in aqueous solution 91
22.Activity coefficients and solubilities of sparinglysoluble electrolytes 95
23.Analytical boundary method for transportnumbers 98
24.The Bronsted theory of acids (strengths of inorganic acids in glacial acetic acid) 103
25.Conductimetric titration of mixtures 109
26.The Debye-Hǖckel theory and weak electrolytes 112
27.Ion-association:Bjerrum’s theory(ion-pair and triple-ion formation) 115
28.Ionic product for water(Kw)by the e.m.f.method 121
29.The Onsager equation and its modifications 124
30.Potentiometry at constant intensity 128
31.Thermodynamic ionization constants of weakelectrolytes 133
32.Thermodynamic transfer quantities by e.m.f.measurements 136
33.“Zwitterions” 140
Ⅳ.KINETICS 147
34.Catalytic decomposition of hydrogen peroxide 149
35.Conductimetric study of the kinetics of hydrolysis of tertiary butyl iodide 153
36.Decomposition of ammonia on a tungstensurface 158
37.Dilatometric study of reaction kinetics 162
38.Energies and entropies of activation of isomericrearrangements 166
39.Isomerization equilibrium and kinetics in aqueous solution 172
40.Method of ratio variation 176
41.Primary salt effect 179
42.Secondary salt effect 185
43.Spectroscopic study of the alcoholysis of cinnamal chloride 190
44.Stirred-flow reactor 193
Ⅴ.PHOTOCHRMISTRY 197
45.Photobromination of cinnamic acid(chainreaction) 199
46.Photocatalysis:the photolysis of uranyl oxalate(uranyl-oxalate aotinometer) 203
47.Photochemical dimerization of anthraoene(photo-stationary state) 207
48.Photohydrolysis of monochloroacetic acid(quan-tum efficiency) 213
49.Photosensitization of chemical reactions(the Eder reaction) 218
50.The oxidation of ferrous iron by iodine under the action of ultra-violet radiation 221
Ⅵ.SPECTROSCOPY 225
51.Deviations from the Beer-Lambert Law 227
52.Indicator constants by spectrophotometry 233
53.Infra-red spectra and chemical properties of molecules 236
54.Ion-association by spectrophotometry 240
55.Isobiestic point 245
56.Moment of inertia, internuclear distance, and bond strength of HI by infra-red spectra 250
57.Quenching of fluorescence 257
58.Spectrophotometric determination of molecularweights 264
59.Spectroscopic determination of equilibrium con-stants of molecular compounds (charge-transfer spectra) 267
60.Spectroscopic study of the dimerization of ethanol in non-polar solvents 270
Ⅶ. THERMODYNAMICS 275
61.Activities of electrolytic solutes by the freezing-point method 277
62.Activities from vapour-pressure data 281
63.Activity of thallium in amalgams at 25℃ 286
64.Partial molal volumes 291
65.Partial molal volumes in regular solutions 296
66.Solubility of naphthalene in various solvents(ideal and non-ideal solutions) 299
67.Thermal dissociation of ferric bromide 304
68.Thermodynamic functions of the reaction be-tween malonic acid and some lanthanons 308
69.Thermodynamics of vaporization of liquids 314
Ⅷ.VARIOUS 319
70.Azeotropie distillation(determination of water content) 321
71.Dipole moment of 1:8-dichloronaphthalene by Guggenheim’s method 326
72.Donnan equilibria 329
73.Enthalpy titrations 334
74.The Hammett indicator acidity function H 340
75.Liquid-liquid adsorption of soluble fatty acids(Gibbs’ and Szyszkowski’s equations) 347
76.Magnetic susceptibility (by the Gouy method) 353
77.Molecular weight determination by “isothermic distillation” (Barger’s opposed twin capillary method) 357
78.The reciprocal salt effect and the Janecke projec-tion (phase rule study) 361
79.The ternary diagram by the wet-residue method(phase rule study) 368
80.The ternary diagram by the synthetic-complex method (phase rule study) 372
81.Thermal decomposition of solids (Prout-Tomp-kins’equation) 375
82.The determination of surface areas of adsorbents by means of the B.E.T.isotherm (physicaladsorption) 380
Appendix:Erros,mistakes,and deviations.Method of least squares 389
Index 399