C Further elements 397
11 Group Ⅲ elements 397
11.0 Crystal structure and electronic structure of boron 397
11.1 Physical properties of boron 399
12 Group Ⅴ elements 404
12.0 Crystal structure and electronic structure 404
12.1 Phosphorus(P) 407
12.2 Arsenic(As) 409
12.3 Antimony(Sb) 412
12.4 Bismuth(Bi) 415
13 Group Ⅵ elements 419
13.0 Crystal structure and electronic structure 419
13.1 Sulfur(S) 422
13.2 Selenium(Se) 424
13.3 Tellurium(Te) 429
D Further binary compounds 434
14 IAx-IBy compounds 434
14.0 Crystal structure and electronic structure 434
14.1 CsAu 434
14.2 RbAu 436
15 Ⅰx-Ⅴy compounds 437
15.0 Crystal structure and electronic structure 437
15.1 Ⅰ-Ⅴ compounds(NaSb,KSb,RbSb,CsSb) 440
15.2 Ⅰ3-Ⅴ compounds 441
15.2.1 Lattice parameters and melting temperatures 441
15.2.2 Li3Sb,Li3Bi 442
15.2.3 Na3Sb 442
15.2.4 K3Sb 442
15.2.5 Rb3Sb 443
15.2.6 Cs3Sb 443
15.2.7 Rb3Bi,Cs3Bi 444
15.3 Ⅰ2-Ⅰ-Ⅴ compounds 444
15.3.1 Na2KSb 444
15.3.2 K2CsSb 444
15.3.3 Na2RbSb,Na2CsSb,K2RbSb,Rb2CsSb 445
16 Ⅰx-Ⅵy compounds 446
16.0 Crystal structure and electronic structure 446
16.1 Cupric oxide(CuO) 449
16.2 Cuprous oxide(Cu2O) 451
16.3 Copper sulfides(Cu2S,Cu2-xS) 454
16.4 Copper selenides(Cu2Se,Cu2 xSe) 456
16.5 Copper tellurides(Cu2Te,Cu2-xTe) 457
16.6 Silver oxides(AgxOy) 458
16.7 Silver sulfide(Ag2S) 459
16.8 Silver selenide(Ag2Se) 461
16.9 Silver telluride(Ag2Te) 462
17 Ⅱx-Ⅳy compounds 464
17.0 Crystal structure and electronic structure 464
17.1 Magnesium silicide(Mg2Si) 465
17.2 Magnesium germanide(Mg2Ge) 468
17.3 Magnesium stannide(Mg2Sn) 470
17.4 Magnesium plumbide(Mg2Pb) 473
17.5 Ca2Si,Ca2Sn,Ca2Pb 475
17.6 BaSi2,BaGe2,SrGe2 475
18 Ⅱx-Ⅴy compounds 476
18.0 Crystal structure and electronic structure 476
18.1 Magnesium arsenide(Mg3As2) 480
18.2 Zinc phosphide(Zn3P2) 481
18.3 Zinc arsenide(Zn3As2) 483
18.4 Cadmium phosphide(Cd3P2) 485
18.5 Cadmium arsenide(Cd3As2) 488
18.6 Zinc phosphide(ZnP2) 490
18.7 Zinc arsenide(ZnAs2) 493
18.8 Cadmium phosphide(CdP2) 495
18.9 Cadmium arsenide(CdAs2) 497
18.10 Cadmium tetraphosphide(CdP4) 499
18.11 Zinc antimonide(ZnSb) 500
18.12 Cadmium antimonide(CdSb) 501
18.13 Zinc antimonide(Zn4Sb3) 503
18.14 Cadmium antimonide(Cd4Sb3) 504
18.15 Cd7P10 505
18.16 Cd6P7 505
19 Ⅱ-Ⅶ2 compounds 507
19.0 Crystal structure and electronic structure 507
19.1 Cadmium dichloride(CdCl2) 509
19.2 Cadmium dibromide(CdBr2) 509
19.3 Cadmium diiodide(CdI2) 510
19.4 Mercury diiodide(HgI2) 512
20 Ⅲx-Ⅵy compounds 515
20.0 Crystal structure and electronic structure 515
20.1 Gallium sulfide(GaS) 520
20.2 Gallium selenide(GaSe) 523
20.3 Gallium telluride(GaTe) 527
20.4 Indium sulfide(InS) 529
20.5 Indium selenide(InSe) 530
20.6 Indium telluride(InTe) 533
20.7 Thallium sulfide(TlS) 535
20.8 Thallium selenide(TlSe) 536
20.9 Thallium telluride(TlTe) 538
20.10 In6S7 539
20.11 In4Se3 540
20.12 In6Se7 540
20.13 In6oSe4o 541
20.14 In5oSe50 542
20.15 In40 Se60 542
20.16 In5Se6 542
20.17 In4Te3 543
20.18 Tl5Te3 543
20.19 TlGaS2 543
20.20 TlGaSe2 545
20.21 TlGaTe2 547
20.22 TlInS2 548
20.23 TlInSe2 550
20.24 TlInTe2 551
21 Ⅲ-Ⅶ compounds 553
21.0 Crystal structure and electronic structure 553
21.1 Thallium fluoride(TlF) 555
21.2 Thallium chloride(TlCl) 556
21.3 Thallium bromide(TlBr) 558
21.4 Thallium iodide(TlI) 561
22 Ⅳ-Ⅴ compounds 563
22.0 Crystal structure and lattice parameters 563
22.1 SiP,GeP 564
22.2 SiAs 564
22.3 GeAs 565
22.4 SiP2,SiAs2 565
22.5 GeAs2 565
23 Ⅳx-Ⅵy compounds 566
23.0 Crystal structure and electronic structure 566
23.1 Germanium sulfide(GeS) 572
23.2 Germanium selenide(GeSe) 574
23.3 Germanium telluride(GeTe) 576
23.4 Tin sulfide(SnS) 578
23.5 Tin selenide(SnSe) 580
23.6 Tin telluride(SnTe) 582
23.7 Lead monoxide(PbO) 585
23.8 Lead sulfide(PbS) 586
23.9 Lead selenide(PbSe) 588
23.10 Lead telluride(PbTe) 590
23.11 Germanium dioxide(GeO2) 593
23.12 Germanium disulfide(GeS2) 595
23.13 Germanium diselenide(GeSe2) 596
23.14 Tin dioxide(SnO2) 597
23.15 Tin disulfide(SnS2) 600
23.16 Tin diselenide(SnSe2) 602
23.17 Si2Te3 603
23.18 Sn2S3,PbSnS3,SnGeS3,PbGeS3 605
24 Ⅳ-Ⅶ2 compounds 606
24.0 Crystal structure 606
24.1 Lead difluoride(PbF2) 606
24.2 Lead dichloride(PbCl2) 608
24.3 Lead dibromide(PbBr2) 609
24.4 Lead diiodide(PbI2) 610
25 Ⅴx-Ⅵy compounds 613
25.0 Crystal structure and electronic structure 613
25.1 Arsenic oxide(As2O3) 617
25.1 Arsenic oxide(As2O3) 617
25.2 Arsenic sulfide(As2S3) 617
25.3 Arsenic selenide(As2Se3) 619
25.4 Arsenic telluride(As2Te3) 620
25.5 Antimony sulfide(Sb2S3) 621
25.6 Antimony selenide(Sb2Se3) 622
25.7 Antimony telluride(Sb2Te3) 624
25.8 Bismuth oxide(Bi2O3) 626
25.9 Bismuth sulfide(Bi2S3) 627
25.10 Bismuth selenide(Bi2Se3) 628
25.11 Bismuth telluride(Bi2Te3) 630
25.12 Realgar(As4S4) 633
26 Ⅴ-Ⅶ3 compounds 634
26.0 Crystal structure and electronic structure 634
26.1 Arsenic triiodide(AsI3) 635
26.2 Antimony triiodide(SbI3) 636
26.3 Bismuth triiodide(BiI3) 637
E Further ternary compounds 640
27 Ⅰx-Ⅳy-Ⅵz compounds 640
27.0 Crystal structure 640
27.1 Ag8GeS6(argyrodite) 641
27.2 Ag8SnS6(canfieldite) 641
27.3 Ag8SiSe6 642
27.4 Ag8GeSe6 642
27.5 Ag8SnSe6 643
27.6 Ag8GeTe6 643
27.7 Cu8GeS6 644
27.8 Cu8GeSe6 644
27.9 Cu4Ge3S5,Cu4Ge3Se5 and Cu4Sn3Se5 644
27.10 Cu4SnS4 644
28 Ix-Ⅴy-Ⅵz compounds 645
28.0 Crystal structure and electronic structure 645
28.1 AgAsS2 646
28.2 AgAsSe2 646
28.3 AgAsTe2 647
28.4 AgSbS2 647
28.5 AgSbSe2 647
28.6 AgSbTe2 648
28.7 AgBiS2 648
28.8 AgBiSe2 649
28.9 AgBiTe2 649
28.10 CuSbSe2 650
28.11 CuSbTe2 650
28.12 CuBiSe2 651
28.13 CuBiTe2 651
28.14 Ag3AsS3 651
28.15 Ag3SbS3 652
29 Ⅱx-Ⅲy-Ⅵz compounds 653
29.0 Crystal structure of Ⅱ-Ⅲ-Ⅵ2 compounds 653
29.1 CdInS2 653
29.2 CdInSe2 654
29.3 CdInTe2 654
29.4 CdTlS2 655
29.5 CdTlSe2 655
29.6 CdTlTe2 656
29.7 HgTlS2 656
30 Ⅲx-Ⅴy-Ⅵz comPounds 657
30.0 Crystal structure of Ⅲ-Ⅴ-Ⅵ2 compounds 657
30.1 TlAsS2 657
30.2 TlSbS2 657
30.3 TlBiS2 658
30.4 TlBiSe2 658
30.5 TlBiTe2 659
30.6 Ga6Sb5Te 659
30.7 In6Sb5Te 659
30.8 In7SbTe6 660
31 Ⅳx-Ⅴy-Ⅵz compounds 661
31.0 Crystal structure 661
31.1 Bi12SiO20 661
31.2 Bi12GeO20 662
31.3 PbSb2S4,GeSb2Te4,GeBi2Te4,SnBi2Te4 662
31.4 GeBi4Te7,GeSb4Te7,PbBi4Te7 663
32 Ⅴ-Ⅵ-Ⅶ compounds 665
32.0 Crystal structure and electronic structure 665
32.1 AsSBr 666
32.2 SbSI 666
32.3 SbSBr 669
32.4 SbSeBr 669
32.5 SbSeI 669
32.6 SbTeI 670
32.7 BiOCl 670
32.8 BiOBr 670
32.9 BiOI 671
32.10 BiSCl 671
32.11 BiSBr 671
32.12 BiSI 671
32.13 BiSeBr 672
32.14 BiSeI 672
32.15 BiTeBr 672
32.16 BiTeI 673
33 Further ternary compounds 674
33.1 Cu3In5Se9 674
33.2 Cu3Ga5Se9 674
33.3 Ag3In5Se9 675
33.4 Ag3Ga5Se9 675
33.5 Cu2Ga4Te7 675
33.6 Cu2In4Te7 676
33.7 CuIn3Te5 676
33.8 AgIn3Te5 677
33.9 AgIn5S8 677
33.10 AgIn9Te14 677
33.11 Cd2SnO4 677
33.12 CdSnO3 678
33.13 Li3CuO3 678
33.14 Hg3PS3,Hg3PS4 678
33.15 Cd4(P,As)2(Cl,Br,I)3 678
F Boron,transition metal and rare earth compounds with semiconducting properties(data only on the enclosed CD-ROM) 679
G Index of substances 680
1 Index of substances for chapters 1...33 680
2 Index of substances for chapters 34...38 685