The Principles Of Applied Electrochemistry Second EditionPDF电子书下载

PART Ⅰ．－GENERAL AND THEORETICAL 1

CHAPTER Ⅰ INTRODUCTORY－POWER 2

Chemical and Electrochemical Methods compared－Electrical Units－Power 3

CHAPTER Ⅱ FARADAY＇S DAWS－CURRENT EFFICIENCY 12

Phenomena of Electrolysis－Faraday＇s Laws－Current Efficiency－Measurement of Quantity of Electricity－Calculation of Current Efficiencies 12

CHAPTER Ⅲ ELECTROLYTIC DISSOCIATION 23

Development of the Theory－Abnormal Osmotic Behaviour of Electrolytes－Conductivity of Electrolytes－Relative Ionic Mobilities－Chemical Properties of Electrolytes－Anomalies of the Electrolytic Dissociation Theory 23

CHAPTER Ⅳ ENERGY RELATIONS 42

Total Energy and Maximum External Work－Change of Free Energy－Relations in Reversible Galvanic Cells－Relations during Reversible Electrolysis－Maximum Work and Affinity 42

CHAPTER Ⅴ ELECTROMOTIVE FORCE 53

CHAPTER Ⅵ ELECTROLYSIS AND POLARISATION－ENERGY EFFICIENCY 73

Polarisation－Energy Efficiency－Polarisation at Individual Electrodes－Mechanism of Electrode Processes－Depolarisation 73

CHAPTER Ⅶ ELECTRODE PROCESSES IN DETAIL－PROCESSES INVOLVING NON-METALLIC IONS 87

Cathodie Evolution of Hydrogen－Anodic Evolution of Oxygen－Theories of Overvoltage－Depolarisation of Hydrogen－Depolarisation of Oxygen－Halogen lon Discharge 87

CHAPTER Ⅷ ELECTRODE PROCESSES IN DETAIL－PROCESSES INVOLVING METALLIC IONS 111

CHAPTER Ⅸ THE ELECTROLYSIS BATH 150

Arrangement－Technical Electrodes and Diaphragms 150

CHAPTER Ⅹ MOLTEN ELECTROLYTES 161

Phenomena of Electrolysis－Metal Fog－Anode Effect 161

CHAPTER Ⅺ GENERAL PRINCIPLES OF ELECTROTHERMICS 170

Electric Heating－General Principles of Electric Furnace Design－Electrical Aspects of Electric Furnace Design 170

CHAPTER Ⅻ ELECTRICAL DISCHARGES IN GASES 190

Gas Ions-Different Types of Discharge－Chemical Effects 190

PART Ⅱ．－SPECIAL AND TECHNICAL 201

CHAPTER ⅩⅢ PRIMARY CELLS 203

General Considerations－Primary Cells in General Use－Fuel Cells 203

CHAPTER ⅩⅣ SECONDARY CELLS 235

General Considerations－Lead Accumulator－Iron Accumulator 235

CHAPTER ⅩⅤ COPPER－SILVER－GOLD 262

Copper Refining，Theory－Copper Refining，Practice－Copper Extraction－Silver Refilling－Gold Refining－Gold Extraction 262

CHAPTER ⅩⅥ ZINC－LEAD－TIN－NICKEL－IRON－MISCELLANEOUS 308

Zinc Extraction，General－Zinc Extraction，Practice－Zinc Refining－Electrometallurgy of Lead－Electrometallurgy of Tin－Electrometallurgy of Nickel－Electrolytic Refining of Iron－Miscellaneous 308

CHAPTER ⅩⅦ ELECTROPLATING AND ELECTROTYPING 351

CHAPTER ⅩⅧ HYPOCHLORITES AND CHLORATES 366

General Theory－Hypochlorites，Theory－Hypochlorites，Technical－Chlorates，Theory Chlorates，Technical 366

CHAPTER ⅩⅨ ALKALI-CHLORINE CELLS 392

CHAPTER ⅩⅩ OTHER ELECTROLYTIC PROCESSES INVOLVING AQUEOUS SOLUTIONS 458

Hydrogen and Oxygen－Lead Salts－Bromine－Regeneration of Chromic Acid－Organic Chemicals－Potassium Permanganate－Perchlorates－Hydrogen Peroxide 458

CHAPTER ⅩⅪ METALS FROM FUSED ELECTROLYTES－CAUSTIC SODA AND CHLORINE FROM FUSED SALT 497

Sodium－Magnesium－Calcium－Cerium－Zinc－Aluminium－Acker Process 497

CHAPTER ⅩⅫ ELECTRIC SMELTING IN THE IRON AND STEEL INDUSTRY 531

Iron and Steel－Ferro Alloys 531

CHAPTER ⅩⅩⅢ ELECTRIC REFINING，MELTING AND HEAT TREATMENT OF STEEL 557

CHAPTER ⅩⅩⅣ ELECTROTHERMICS OF THE NON-FERROUS METALS 599

Smelting Processes－Zinc－Copper－Nickel－Tin－Melting Processes，General－Arc Furnaces－Resistance Furnaces－Comparative Operation Results 599

CHAPTER ⅩⅩⅤ CALCIUM CARBIDE－CALCIUM CYANAMIDE－CYANIDES 632

Carbide，General and Theory－Carbide，Technical－Cyanamide and Cyanides，General and Theory－Cyanamide，Technical－Conversion of Cyanamide into Cyanide，Technical 632

CHAPTER ⅩⅩⅥ OTHER ELECTROTHERMAL PRODUCTS 653

Carborundum and Allied Products－Graphite－Alundum，Silica，Barium Oxide，Sodium Sulphide，etc．－Distillation Products，Carbon Bisulphide，Phosphorus 653

CHAPTER ⅩⅩⅦ THE OXIDATION OF ATMOSPHERIC NITROGEN 671

Theoretical－Early Attempts at Technical Apparatus－Birkeland-Eyde Process－Pauling Process－Schonherr-Hessberger Process－Comparative Efficiency－Working up of Furnace Gases 671

CHAPTER ⅩⅩⅧ OZONE 689

Theoretical－Technical 689

APPENDICES Ⅰ The Degree of Ionisation of Typical Electrolytes 700

APPENDICES Ⅱ Single-Electrode Potentials 701

APPENDICES Ⅲ Oxidation-Reduction Potentials 702

APPENDICES Ⅳ Current Densities Used in Technical Practice 704

APPENDICES Ⅴ Yields and Energy Expenditure in Technical Practice 706

APPENDICES Ⅵ Theoretical Quantities of Electrolytic Products resulting from the Passage of 1 ampere-hour of Electricity 708

INDEX OF AUTHORS AND FIRMS 709

SUBJECT INDEX 715