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Chapter 1 Overview of Chemical Reaction Engineering 1

Part Ⅰ Homogeneous Reactions in Ideal Reactors 11

Chapter 2 Kinetics of Homogeneous Reactions 13

2.1 Concentration-Dependent Term of a Rate Equation 14

2.2 Temperature-Dependent Term of a Rate Equation 27

2.3 Searching for a Mechanism 29

2.4 Predictability of Reaction Rate from Theory 32

Chapter 3 Interpretation of Batch Reactor Data 38

3.1 Constant-volume Batch Reactor 39

3.2 Varying-volume Batch Reactor 67

3.3 Temperature and Reaction Rate 72

3.4 The Search for a Rate Equation 75

Chapter 4 Introduction to Reactor Design 82

Chapter 5 Ideal Reactors for a Single Reaction 90

5.1 Ideal Batch Reactors 91

52. Steady-State Mixed Flow Reactors 94

5.3 Steady-State Plug Flow Reactors 101

Chapter 6 Design for Single Reactions 120

6.1 Size Comparison of Single Reactors 121

6.2 Multiple-Reactor Systems 124

6.3 Recycle Reactor 136

6.4 Autocatalytic Reactions 140

Chapter 7 Design for Parallel Reactions 152

Chapter 8 Potpourri of Multiple Reactions 170

8.1 Irreversible First-Order Reactions in Series 170

8.2 First-Order Followed by Zero-Order Reaction 178

8.3 Zero-Order Followed by First-Order Reaction 179

8.4 Successive Irreversible Reactions of Different Orders 180

8.5 Reversible Reactions 181

8.6 Irreversible Series-Parallel Reactions 181

8.7 The Denbigh Reaction and its Special Cases 194

Chapter 9 Temperature and Pressure Effects 207

9.1 Single Reactions 207

9.2 Multiple Reactions 235

Chapter 10 Choosing the Right Kind of Reactor 240

Part Ⅱ Flow Patterns, Contacting, and Non-Ideal Flow 255

Chapter 11 Basics of Non-Ideal Flow 257

11.1 E, the Age Distribution of Fluid, the RTD 260

11.2 Conversion in Non-Ideal Flow Reactors 273

Chapter 12 Compartment Models 283

Chapter 13 The Dispersion Model 293

13.1 Axial Dispersion 293

13.2 Correlations for Axial Dispersion 309

13.3 Chemical Reaction and Dispersion 312

Chapter 14 The Tanks-in-Series Model 321

14.1 Pulse Response Experiments and the RTD 321

14.2 Chemical Conversion 328

Chapter 15 The Convection Model for Laminar Flow 339

15.1 The Convection Model and its RTD 339

15.2 Chemical Conversion in Laminar Flow Reactors 345

Chapter 16 Earliness of Mixing, Segregation and RTD 350

16.1 Self-mixing of a Single Fluid 350

16.2 Mixing of Two Miscible Fluids 361

Part Ⅲ Reactions Catalyzed by Solids 367

Chapter 17 Heterogeneous Reactions - Introduction 369

Chapter 18 Solid Catalyzed Reactions 376

18.1 The Rate Equation for Surface Kinetics 379

18.2 Pore Diffusion Resistance Combined with Surface Kinetics 381

18.3 Porous Catalyst Particles 385

18.4 Heat Effects During Reaction 391

18.5 Performance Equations for Reactors Containing Porous Catalyst Particles 393

18.6 Experimental Methods for Finding Rates 396

18.7 Product Distribution in Multiple Reactions 402

Chapter 19 The Packed Bed Catalytic Reactor 427

20.3 The K-L Model for BFB 445

Chapter 20 Reactors with Suspended Solid Catalyst, Fluidized Reactors of Various Types 447

20.1 Background Information About Suspended Solids Reactors 447

20.2 The Bubbling Fluidized Bed—BFB 451

20.4 The Circulating Fluidized Bed—CFB 465

20.5 The Jet Impact Reactor 470

Chapter 21 Deactivating Catalysts 473

21.1 Mechanisms of Catalyst Deactivation 474

21.2 The Rate and Performance Equations 475

21.3 Design 489

Chapter 22 G/L Reactions on Solid Catalyst: Trickle Beds, Slurry Reactors, Three-Phase Fluidized Beds 500

22.1 The General Rate Equation 500

22.2 Performance Equations for an Excess of B 503

22.3 Performance Equations for an Excess of A 509

22.4 Which Kind of Contactor to Use 509

22.5 Applications 510

Part Ⅳ Non-Catalytic Systems 521

Chapter 23 Fluid-Fluid Reactions: Kinetics 523

23.1 The Rate Equation 524

Chapter 24 Fluid-Fluid Reactors: Design 540

24.1 Straight Mass Transfer 543

24.2 Mass Transfer Plus Not Very Slow Reaction 546

Chapter 25 Fluid-Particle Reactions: Kinetics 566

25.1 Selection of a Model 568

25.2 Shrinking Core Model for Spherical Particles of Unchanging Size 570

25.3 Rate of Reaction for Shrinking Spherical Particles 577

25.4 Extensions 579

25.5 Determination of the Rate-Controlling Step 582

Chapter 26 Fluid-Particle Reactors: Design 589

Part Ⅴ Biochemical Reaction Systems 609

Chapter 27 Enzyme Fermentation 611

27.1 Michaelis-Menten Kinetics (M-M kinetics) 612

27.2 Inhibition by a Foreign Substance--Competitive and Noncompetitive Inhibition 616

Chapter 28 Microbial Fermentation-Introduction and Overall Picture 623

Chapter 29 Substrate-Limiting Microbial Fermentation 630

29.1 Batch (or Plug Flow) Fermentors 630

29.2 Mixed Flow Fermentors 633

29.3 Optimum Operations of Fermentors 636

Chapter 30 Product-Limiting Microbial Fermentation 645

30.1 Batch or Plus Flow Fermentors for n = 1 646

30.2 Mixed Flow Fermentors for n = 1 647

Appendix 655

Name Index 662

Subject Index 665