The Determination of Hydrogen Ions Third EditionPDF电子书下载

CHAPTER Ⅰ INTRODUCTION AND THE SIMPLER EQUILIBRIUM EQUATIONS FOR ACIDS AND BASES 1

CHAPTER Ⅱ SOME SPECIAL ASPECTS OF ACID-BASE EQUILIBRIA 35

CHAPTER Ⅲ OUTLINE OF A COLORIMETRIC METHOD 62

CHAPTER Ⅳ CHOICE OF INDICATORS 67

CHAPTER Ⅴ THEORY OF INDICATORS 99

CHAPTER Ⅵ APPROXIMATE DETERMINATIONS WITH INDICATORS 119

CHAPTER Ⅶ THE APPLICATION OF SPECTROPHOTOMETRY,COLORIMETRY,ETC 141

CHAPTER Ⅷ SOURCES OF ERROR IN COLORIMETRIC DETERMINATIONS 177

CHAPTER Ⅸ STANDARD BUFFER SOLUTIONS 192

CHAPTER Ⅹ OUTLINE OF THE ＂HYDROGEN-ELECTRODE＂ METHOD 221

CHAPTER Ⅺ ON CHANGES OF FREE-ENERGY 230

CHAPTER Ⅻ THEORY OF THE HYDROGEN-ELECTRODE 251

CHAPTER ⅩⅢ POTENTIAL DIFFERENCES AT LIQUID JUNCTIONS 264

CHAPTER ⅩⅣ HYDROGEN HALF-CELLS 281

CHAPTER ⅩⅤ CALOMEL AND OTHER STANDARD HALF-CELLS 303

CHAPTER ⅩⅥ THE POTENTIOMETER,NULL-POINT INSTRUMENTS AND ACCESSORY EQUIPMENT 317

CHAPTER ⅩⅦ HYDROGEN GENERATORS,WIRING,INSULATION,SHIELDING,TEMPERATURE CONTROL,PURIFICATION OF MERCURY 350

CHAPTER ⅩⅧ OXIDATION-REDUCTION POTENTIALS 367

CHAPTER ⅩⅨ THE QUINHYDRONE AND SIMILAR HALF-CELLS 404

CHAPTER ⅩⅩ METAL-OXIDE ELECTRODES．THE GLASS ELECTRODE．THE OXYGEN ELECTRODE 423

CHAPTER ⅩⅪ SOURCES OF ERROR IN ELECTROMETRIC MEASUREMENTS 434

CHAPTER ⅩⅫ TEMPERATURE COEFFICIENTS 448

CHAPTER ⅩⅩⅢ STANDARDIZATION OF pH-MEASUREMENTS 461

CHAPTER ⅩⅩⅣ STANDARD SOLUTIONS FOR THE ROUTINE CHECKING OF HYDROGEN ELECTRODE MEASUREMENTS 483

CHAPTER ⅩⅩⅤ THE THEORY OF DEBYE AND H？CKEL 489

CHAPTER ⅩⅩⅥ SUPPLEMENTARY METHODS 513

CHAPTER ⅩⅩⅦ AN ALTERNATE METHOD OF FORMULATING ACID-BASE EQUILIBRIA 519

CHAPTER ⅩⅩⅧ ELEMENTARY THEORY OF TITRATION 530

CHAPTER ⅩⅩⅨ NON-AQUEOUS SOLUTIONS 539

CHAPTER ⅩⅩⅩ 549

APPLICATIONS 549

BIBLIOGRAPHY 587

APPENDICES 672

TABLE A．ARBITRARILY STANDARDIZED VALUES FOR HALF-CELLS 672

TABLE B．RELATION OF [H+] TO pH 673

TABLE C．FACTORS FOR CONCENTRATION CELLS 0℃．TO 70℃ 674

TABLE D．CORRECTION OF BAROMETER READING FOR TEMPERATURE 675

TABLE E．BAROMETRIC CORRECTIONS FOR H-ELECTRODE POTENTIALS 676

TABLE F．VALUES OF LOG α/1-α AND OF LOG α/1-α MULTIPLIED BY THE TEMPERATURE FACTORS FOR CONCENTRATION CELLS 677

TABLE G．DISSOCIATION EXPONENTS OF ACIDS 678

TABLE H．DISSOCIATION CONSTANTS AND ASSOCIATION EXPONENTS OF BASES 679

TABLE I．DISSOCIATION EXPONENTS AND ASSOCIATION EXPONENTS OF AMINO ACIDS 680

TABLE J．HALF TRANSFORMATION POINTS OF ALKALOIDS 681

TABLE K．RELATION OF PERCENTAGE REDUCTION TO POTENTIAL AT CONSTANT pH 682

TABLE L．E′o VALUES FOR SEVERAL OXIDATION REDUCTION INDICATORS AT 30℃ 683

TABLE M．SYMBOLS AND CONVENIENT FORMULAS 684

TABLE N．DEFINITIONS FOR THE MOST PART NOT INCLUDED IN THE TEXT 684

TABLE O．TABLE OF LOGARITHMS 690

INDEX OF AUTHORS 693

INDEX OF SUBJECTS 703