The Radiation Chemistry of Water and Aqueous SolutionsPDF电子书下载

1．RADIATIONS:HOW THEIR ENERGY IS DISSIPATED 1

Light-particle radiations 1

Energy loss of electrons in water 3

Radiation units 8

Heavy particles 10

Picture of irradiated water 12

2．EXPERIMENTAL METHODS AND DOSIMETRY 13

Radiation sources 13

Water purification 18

Dosimetry 20

3．THE FREE RADICAL THEORY 24

Indirect action 24

Molecular and radical yields 24

Reaction schemes 26

Origin and constitution of radicals 27

Reaction kinetics 29

Chain reactions 30

4．REACTIONS INDUCED BY GAMMA-RAYS IN SOME SIMPLE SOLUTIONS;MAGNITUDES OF THE MOLECULAR AND RADICAL YIELDS 32

Definitions and notation 32

The hydrogen yield 33

FeSO4 oxidation:the hydrogen atom yield 34

Ceric sulfate reduction:yields of OH and H2O2 38

Reduction of oxygen 40

The vanadium system 41

Effect of acid concentration 43

The yields in neutral solution 44

Effects of other variables 48

10．FURTHER OBSERVATIONS ON SOLUTIONS OF ORGANIC COMPOUNDS 142

Hydrocarbons 142

Acids 144

Amino acids 148

Alcohols and phenols 150

Esters and ketones 153

Carbohydrates 154

Steroids 155

Nitrogen compounds 157

Sulfur compounds 160

Chlorine compounds 163

Polymer solutions 165

Dyes 169

11．SOLUTIONS OF LARGE MOLECULES OF BIOLOGICAL INTEREST 173

Reaction kinetics 173

Enzyme solutions 176

Other proteins 182

Nucleic acid 185

Applications to radiobiology 189

NAME INDEX 193

SUBJECT INDEX 199