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Alder ene reaction 1

Aldol condensation 3

Algar-Flynn-Oyamada reaction 5

Allan-Robinson reaction 8

Appel reaction 10

Arndt-Eistert homologation 12

Baeyer-Villiger oxidation 14

Baker-Venkataraman rearrangement 16

Bamberger rearrangement 18

Bamford-Stevens reaction 20

Barbier coupling reaction 22

Bargellini reaction 24

Bartoli indole synthesis 26

Barton radical decarboxylation 28

Barton-McCombie deoxygenation 30

Barton nitrite photolysis 32

Barton-Zard reaction 34

Batcho-Leimgruber indole synthesis 36

Baylis-Hillman reaction 39

Beckmann rearrangement 41

Beirut reaction 43

Benzilic acid rearrangement 45

Benzoin condensation 47

Bergman cyclization 49

Biginelli pyrimidone synthesis 51

Birch reduction 53

Bischler-M？hlau indole synthesis 55

Bischler-Napieralski reaction 57

Blaise reaction 59

Blanc chloromethylation 61

Blum aziridine synthesis 63

Boekelheide reaction 65

Boger pyridine synthesis 67

Borch reductive amination 69

Borsche-Drechsel cyclization 71

Boulton-Katritzky rearrangement 73

Bouveault aldehyde synthesis 75

Bouveault-Blanc reduction 77

Boyland-Sims oxidation 79

Bradsher reaction 81

Brook rearrangement 83

Brown hydroboration 85

Bucherer carbazole synthesis 87

Bucherer reaction 90

Bucherer-Bergs reaction 92

Büchner-Curtius-Schlotterbeck reaction 94

Büchner method of ring expansion 96

Buchwald-Hartwig C-N bond and C-O bond formation reactions 98

Burgess dehydrating reagent 100

Cadiot-Chodkiewicz coupling 102

Camps quinolinol synthesis 104

Cannizzaro dispropotionation 107

Carroll rearrangement 109

Castro-Stephens coupling 112

Chan alkyne reduction 114

Chan-Lam coupling reaction 116

Chapman rearrangement 118

Chichibabin pyridine synthesis 120

Chugaev reaction 123

Ciamician-Dennsted rearrangement 125

Claisen condensation 127

Claisen isoxazole synthesis 129

Claisen rearrangement 131

Abnormal Claisen rearrangement 133

Eschenmoser-Claisen amide acetal rearrangement 135

Ireland-Claisen(silyl ketene acetal)rearrangement 137

Johnson-Claisen(orthoester)rearrangement 139

Clemmensen reduction 141

Combes quinoline synthesis 144

Conrad-Limpach reaction 147

Cope elimination reaction 149

Cope rearrangement 151

Oxy-Cope rearrangement 152

Anionic oxy-Cope rearrangement 153

Corey-Bakshi-Shibata(CBS)reduction 154

Corey-Chaykovsky reaction 157

Corey-Fuchs reaction 160

Corey-Kim oxidation 162

Corey-Nicolaou macrolactonization 164

Corey-Seebach dithiane reaction 166

Corey-Winter olefin synthesis 168

Cfiegee glycol cleavage 171

Criegee mechanism of ozonolysis 173

Curtius rearrangement 175

Dakin oxidation 177

Dakin-West reaction 179

Danheiser annulation 181

Darzens glycidic ester condensation 183

Davis chiral oxaziridine reagent 185

Delépine amine synthesis 187

de Mayo reaction 189

Demjanov rearrangement 191

Tiffeneau-Demjanov rearrangement 193

Dess-Martin oxidation 195

Dieckmann condensation 197

Diels-Alder reaction 199

Dienone-phenol rearrangement 202

Di-π-methane rearrangement 204

Doebner quinoline synthesis 206

D？tz reaction 208

Dowd-Beckwith ring expansion 210

Erlenmeyer-Pl？chl azlactone synthesis 212

Eschenmoser-Tanabe fragmentation 214

Eschweiler-Clarke reductive alkylation of amines 216

Evans aldol reaction 218

Favorskii rearrangement and quasi-Favorskii rearrangement 220

Feist-Bénary furan synthesis 222

Ferrier carbocyclization 224

Ferrier glycal allylic rearrangement 227

Fiesselmann thiophene synthesis 230

Fischer indole synthesis 233

Fischer oxazole synthesis 235

Fleming-Tamao oxidation 237

Tamao-Kumada oxidation 239

Friedel-Crafts reaction 240

Ffiedl？nder quinoline synthesis 243

Fries rearrangement 245

Fukuyama amine synthesis 247

Fukuyama reduction 249

Gabriel synthesis 251

Ing-Manske procedure 253

Gabriel-Colman rearrangement 255

Gassman indole synthesis 257

Gattermann-Koch reaction 259

Gewald aminothiophene synthesis 261

Glaser coupling 263

Eglinton coupling 265

Gomberg-Bachmann reaction 267

Gould-Jacobs reaction 269

Grignard reaction 271

Grob fragmentation 273

Guareschi-Thorpe condensation 275

Hajos-Wiechert reaction 277

Haller-Bauer reaction 279

Hantzsch dihydropyridine synthesis 281

Hantzsch pyrrole synthesis 283

Heck reaction 285

Heteroaryl Heck reaction 287

Hegedus indole synthesis 289

Hell-Volhard-Zelinsky reaction 291

Henry nitroaldol reaction 293

Hinsberg synthesis of thiophene deritvatives 295

Hiyama cross-coupling reaction 297

Hiyama-Denmark cross-coupling reaction 299

Hofmann rearrangement 302

Hofmann-L？ffler-Freytag reaction 304

Horner-Wadsworth-Emmons reaction 306

Houben-Hoesch synthesis 308

Hunsdiecker-Borodin reaction 310

Hurd-Mori 1,2,3-thiadiazole synthesis 312

Jacobsen-Katsuki epoxidation 314

Japp-Klingemann hydrazone synthesis 316

Jones oxidation 318

Julia-Kocienski olefination 321

Julia-Lythgoe olefination 323

Kahne-Crich glycosidation 325

Keck macrolactonization 327

Knoevenagel condensation 329

Knorr pyrazole synthesis 331

Paal-Knorr pyrrole synthesis 333

Koch-Haaf carbonylation 335

Koenig-Knorr glycosidation 337

Kolbe-Schmitt reaction 339

Kostanecki reaction 341

Kr？hnke pyridine synthesis 343

Kumada cross-coupling reaction 345

Lawesson's reagent 348

Leuckart-Wallach reaction 350

Lossen rearrangement 352

McFadyen-Stevens reduction 354

McMurry coupling 356

MacMillan catalyst 358

Mannich reaction 361

Marshall boronate fragmentation 363

Martin's sulfurane dehydrating reagent 365

Masamune-Roush conditions 367

Meerwein-Ponndorf-Verley reduction 369

Meisenheimer complex 371

[1,2]-Meisenheimer rearrangement 372

[2,3]-Meisenheimer rearrangement 374

Meth-Cohn quinoline synthesis 376

Meyers oxazoline method 378

Meyer-Schuster rearrangement 380

Michael addition 382

Michaelis-Arbuzov phosphonate synthesis 384

Midland reduction 386

Mislow-Evans rearrangement 388

Mitsunobu reaction 390

Miyaura borylation 392

Moffatt oxidation 394

Montgomery coupling 396

Morgan-Walls reaction 399

Pictet-Hubert reaction 400

Mori-Ban indole synthesis 401

Mukaiyama aldol reaction 403

Mukaiyama Michael addition 405

Mukaiyama reagent 406

Myers-Saito cyclization 408

Nazarov cyclization 410

Neber rearrangement 412

Nef reaction 414

Negishi cross-coupling reaction 416

Nenitzescu indole synthesis 418

Nicholas reaction 420

Nicolaou dehydrogenation 422

Nicolaou hydroxy-dithioketal cyclization 424

Nicolaou hydroxy-ketone reductive cyclic ether formation 426

Nicolaou oxyselenation 428

Noyori asymmetric hydrogenation 430

Nozaki-Hiyama-Kishi reaction 432

Oppenauer oxidation 434

Overman rearrangement 436

Paal thiophene synthesis 438

Paal-Knorr furan synthesis 440

Parham cyclization 442

Passerini reaction 444

Paternó-Büichi reaction 446

Pauson-Khand cyclopentenone synthesis 448

Payne rearrangement 450

Pechmann coumarin synthesis 452

Perkin reaction 454

Petasis reaction 456

Peterson olefination 458

Pictet-Gams isoquinoline synthesis 460

Pictet-Spengler tetrahydroisoquinoline synthesis 462

Pinacol rearrangement 464

Pinner reaction 466

Polonovski reaction 468

Polonovski-Potier rearrangement 470

Pomeranz-Fritsch reaction 472

Schlitter-Müller modification 473

Prévost trans-dihydroxylation 475

Woodward cis-dihydroxylation 476

Prins reaction 478

Pschorr cyclization 480

Pummerer rearrangement 483

Ramberg-B？cklund reaction 485

Reformatsky reaction 487

Regitz diazo synthesis 489

Reimer-Tiemann reaction 492

Reissert aldehyde synthesis 494

Reissert indole synthesis 497

Ring-closing metathesis 499

Ritter reaction 501

Robinson annulation 503

Robinson-Gabriel synthesis 505

Robinson-Sch？pf reaction 507

Rosenmund reduction 509

Rubottom oxidation 511

Rupe rearrangement 513

Saegusa oxidation 515

Sakurai allylation reaction 518

Sandmeyer reaction 520

Schiemann reaction 522

Schmidt reaction 524

Schmidt's trichloroacetimidate glycosidation reaction 526

Shapiro reaction 529

Sharpless asymmetric amino hydroxylation 531

Sharpless asymmetric epoxidation 533

Sharpless asymmetric dihydroxylation 536

Sharpless olefin synthesis 540

Simmons-Smith reaction 543

Skraup quinoline synthesis 545

Doebner-von Miller reaction 547

Smiles rearrangement 549

Newman-Kwart reaction 551

Truce-Smile rearrangement 553

Sommelet reaction 555

Sommelet-Hauser rearrangement 557

Sonogashira reaction 559

Staudinger ketene cycloaddition 561

Staudinger reduction 563

Sternbach benzodiazepine synthesis 565

Stetter reaction 567

Still-Gennari phosphonate reaction 569

Stille coupling 571

Stille-Kelly reaction 573

Stobbe condensation 575

Stork enamine reaction 577

Strecker amino acid synthesis 579

Suzuki coupling 581

Swern oxidation 583

Takai iodoalkene synthesis 585

Tebbe olefination 587

Petasis alkenylation 587

TEMPO-mediated oxidation 589

Thorpe-Ziegler reaction 592

Tsuji-Trost allylation 594

Ugi reaction 596

Ullmann reaction 599

van Leusen oxazole synthesis 601

Vilsmeier-Haack reaction 603

Vilsmeier mechanism for acid chloride formation 605

Vinylcyclopropane-cyclopentene rearrangement 606

von Braun reaction 608

Wacker oxidation 610

Wagner-Meerwein rearrangement 612

Weiss-Cook reaction 614

Wharton oxygen transposition reaction 616

Willgerodt-Kindler reaction 618

Wittig reaction 621

Schlosser modification of the Wittig reaction 622

[l,2]-Wittig rearrangement 624

[2,3]-Wittig rearrangement 626

Wohl-Ziegler reaction 628

Wolff rearrangement 630

Wolff-Kishner reduction 632

Yamaguchi esterification 634

Zincke reaction 637

Subject Index 641