Chapter 1 Overview of Chemical Reaction Engineering 1
Part Ⅰ Homogeneous Reactions in Ideal Reactors 11
Chapter 2 Kinetics of Homogeneous Reactions 13
2.1 Concentration-Dependent Term of a Rate Equation 14
2.2 Temperature-Dependent Term of a Rate Equation 27
2.3 Searching for a Mechanism 29
2.4 Predictability of Reaction Rate from Theory 32
Chapter 3 Interpretation of Batch Reactor Data 38
3.1 Constant-volume Batch Reactor 39
3.2 Varying-volume Batch Reactor 67
3.3 Temperature and Reaction Rate 72
3.4 The Search for a Rate Equation 75
Chapter 4 Introduction to Reactor Design 82
Chapter 5 Ideal Reactors for a Single Reaction 90
5.1 Ideal Batch Reactors 91
52. Steady-State Mixed Flow Reactors 94
5.3 Steady-State Plug Flow Reactors 101
Chapter 6 Design for Single Reactions 120
6.1 Size Comparison of Single Reactors 121
6.2 Multiple-Reactor Systems 124
6.3 Recycle Reactor 136
6.4 Autocatalytic Reactions 140
Chapter 7 Design for Parallel Reactions 152
Chapter 8 Potpourri of Multiple Reactions 170
8.1 Irreversible First-Order Reactions in Series 170
8.2 First-Order Followed by Zero-Order Reaction 178
8.3 Zero-Order Followed by First-Order Reaction 179
8.4 Successive Irreversible Reactions of Different Orders 180
8.5 Reversible Reactions 181
8.6 Irreversible Series-Parallel Reactions 181
8.7 The Denbigh Reaction and its Special Cases 194
Chapter 9 Temperature and Pressure Effects 207
9.1 Single Reactions 207
9.2 Multiple Reactions 235
Chapter 10 Choosing the Right Kind of Reactor 240
Part Ⅱ Flow Patterns, Contacting, and Non-Ideal Flow 255
Chapter 11 Basics of Non-Ideal Flow 257
11.1 E, the Age Distribution of Fluid, the RTD 260
11.2 Conversion in Non-Ideal Flow Reactors 273
Chapter 12 Compartment Models 283
Chapter 13 The Dispersion Model 293
13.1 Axial Dispersion 293
13.2 Correlations for Axial Dispersion 309
13.3 Chemical Reaction and Dispersion 312
Chapter 14 The Tanks-in-Series Model 321
14.1 Pulse Response Experiments and the RTD 321
14.2 Chemical Conversion 328
Chapter 15 The Convection Model for Laminar Flow 339
15.1 The Convection Model and its RTD 339
15.2 Chemical Conversion in Laminar Flow Reactors 345
Chapter 16 Earliness of Mixing, Segregation and RTD 350
16.1 Self-mixing of a Single Fluid 350
16.2 Mixing of Two Miscible Fluids 361
Part Ⅲ Reactions Catalyzed by Solids 367
Chapter 17 Heterogeneous Reactions - Introduction 369
Chapter 18 Solid Catalyzed Reactions 376
18.1 The Rate Equation for Surface Kinetics 379
18.2 Pore Diffusion Resistance Combined with Surface Kinetics 381
18.3 Porous Catalyst Particles 385
18.4 Heat Effects During Reaction 391
18.5 Performance Equations for Reactors Containing Porous Catalyst Particles 393
18.6 Experimental Methods for Finding Rates 396
18.7 Product Distribution in Multiple Reactions 402
Chapter 19 The Packed Bed Catalytic Reactor 427
20.3 The K-L Model for BFB 445
Chapter 20 Reactors with Suspended Solid Catalyst, Fluidized Reactors of Various Types 447
20.1 Background Information About Suspended Solids Reactors 447
20.2 The Bubbling Fluidized Bed—BFB 451
20.4 The Circulating Fluidized Bed—CFB 465
20.5 The Jet Impact Reactor 470
Chapter 21 Deactivating Catalysts 473
21.1 Mechanisms of Catalyst Deactivation 474
21.2 The Rate and Performance Equations 475
21.3 Design 489
Chapter 22 G/L Reactions on Solid Catalyst: Trickle Beds, Slurry Reactors, Three-Phase Fluidized Beds 500
22.1 The General Rate Equation 500
22.2 Performance Equations for an Excess of B 503
22.3 Performance Equations for an Excess of A 509
22.4 Which Kind of Contactor to Use 509
22.5 Applications 510
Part Ⅳ Non-Catalytic Systems 521
Chapter 23 Fluid-Fluid Reactions: Kinetics 523
23.1 The Rate Equation 524
Chapter 24 Fluid-Fluid Reactors: Design 540
24.1 Straight Mass Transfer 543
24.2 Mass Transfer Plus Not Very Slow Reaction 546
Chapter 25 Fluid-Particle Reactions: Kinetics 566
25.1 Selection of a Model 568
25.2 Shrinking Core Model for Spherical Particles of Unchanging Size 570
25.3 Rate of Reaction for Shrinking Spherical Particles 577
25.4 Extensions 579
25.5 Determination of the Rate-Controlling Step 582
Chapter 26 Fluid-Particle Reactors: Design 589
Part Ⅴ Biochemical Reaction Systems 609
Chapter 27 Enzyme Fermentation 611
27.1 Michaelis-Menten Kinetics (M-M kinetics) 612
27.2 Inhibition by a Foreign Substance--Competitive and Noncompetitive Inhibition 616
Chapter 28 Microbial Fermentation-Introduction and Overall Picture 623
Chapter 29 Substrate-Limiting Microbial Fermentation 630
29.1 Batch (or Plug Flow) Fermentors 630
29.2 Mixed Flow Fermentors 633
29.3 Optimum Operations of Fermentors 636
Chapter 30 Product-Limiting Microbial Fermentation 645
30.1 Batch or Plus Flow Fermentors for n = 1 646
30.2 Mixed Flow Fermentors for n = 1 647
Appendix 655
Name Index 662
Subject Index 665