CHAPTER 1 INTRODUCTION TO MATERIALS SCIENCE AND ENQINEERINQ 1
1.1 MATERIALS AND ENGINEERING 1
1.2 MATERALS SCIENCE AND ENGINEERING 3
1.3 TYPES OF MATERIALS 5
1.4 COMPETITION AMONG MATERIALS 9
1.5 FUTURE TRENDS IN MATERIALS USAGE 11
CHAPTER 2 ATOMIC STRUCTURE AND DONDING 17
2.1 THE STRUCTURE OF ATOMS 17
2.2 ATOMIC NUMBERS AND ATOMIC MASSES 18
2.3 THE ELECTRONIC STRUCTURE OF ATOMS 21
2.4 TYPES OF ATOMIC AND MOLECULAR BONDS 35
2.5 IONIC BONDING 35
2.6 COVALENT BONDING 42
2.7 METALLIC BONDING 49
2.8 SECONDARY BONDING 52
2.9 MIXED BONDING 56
CHAPTER3 CRYSTAL STRUCTVRES AND CRYSTAL QEOMETRY 63
3.1 THE SPACE LATTICE AND UNIT CELLS 63
3.2 CRYSTAL SYSTEMS AND BRAVAIS LATTICES 64
3.3 PRINCIPAL METALLIC CRYSTALSTRUCTURES 66
3.4 ATOM POSITIONS IN CUBIC UNIT CELLS 75
3.5 DIRECTIONS IN CUBIC UNIT CELLS 76
3.6 MILLER INDICES FOR CRYSTALLOGRAPHIC PLANES IN CUBIC UNIT CELLS 78
3.7 CRYSTALLOGRAPHIC PLANES AND DIRECTIONS IN HEXAGONAL UNIT CELLS 83
3.8 COMPARISON OF FCC, HCP, AND BCC CRYSTAL STRUCTURES 85
3.9 VOLUME, PLANAR, AND LINEAR DENSITY UNIT CELL CALCULATIONS 87
3.10 POLYMORPHISM OR ALLOTROPY 92
3.11 CRYSTAL STRUCTURE ANALYSIS 94
CHAPTER 4 SOLIDIFICATION, CRYSTALLINE IMPERFECTIONS, AND DIFFUSION IN SOLIDS 113
4.1 SOLIDIFICATION OF METALS 113
4.2 SOLIDIFICATION OF SINGLE CRYSTALS 122
4.3 METALLIC SOLID SOLUTIONS 125
4.4 CRYSTALLINE IMPERFECTIONS 129
4.5 RATE PROCESSES IN SOLIDS 142
4.6 ATOMIC DIFFUSION IN SOLIDS 147
4.7 INDUSTRIAL APPLICATIONS OF DIFFUSION PROCESSES 153
4.8 EFFECT OF TEMPERATURE ON DIFFUSION IN SOLIDS 161
CHAPTER 5 ELECTRICAL PROPERTIES OF MATERIALS 173
5.1 ELECTRICAI CONDUC?ON IN MLTALS 173
5.2 ENERGY BAND MODEL FOR ELECTRICAL CONDUCTION 184
5.3 INTRINSIC SEMICONDUCTORS 187
5.4 EXTRINSIC SEMICONDUCTORS 204
5.5 SEMICO?? 204
5.6 MICRO? 212
CHAPTER 6 MECHANICAL PROPERTIES OFME? 231
6.1 THE PROCESSING METALS AND ALLOYS 231
6.2 STRESS AND STRAIN IN METALS 242
6.3 THE TENSILE T ES T AND THE ENGINEERING STRESSSTRAIN DIAGRAM 247
6.4 HARDNESS AND HARDNESS TESTING 255
6.5 PLASTIC DEFORMATTON OF METAL SINGLE CRYSTALS 258
6.6 PLASTIC DEFORMATION OF POLYCRYSTALLINE METALS 268
6.7 SOLID-SOLUTION STRENGTHENING OF METALS 272
6.8 RECOVERY AND RECRYSTALLIZATION OF PLASTICALLY DEFORMED METALS 273
6.9 FRACTURE OF METALS 279
6.10 FATIGUE OF METALS 284
6.11 CREEP AND STRESS RUPTURE OF METALS 288
CHAPTER 7 POLYMERIC MATERIALS 299
7.1 INTRODUCTION 299
7.2 POLYMERIZATION REACTIONS 302
7.3 INDUSTRIAL POLYMERIZATION METHODS 313
7.4 CRYSTALLINITY AND STEREOISOMERISM IN SOME THERMOPLASTICS 315
7.5 PROCESSING OF PLASTIC MATERIALS 320
7.6 GENERAL-PURPOSE THERMOPLASTICS 326
7.7 ENGINEERING THERMOPLASTICS 342
7.8 THERMOSETTING PLASTICS (THERMOSETS) 354
7.9 ELASTOMERS (RUBBERS) 364
7.10 DEFORMATION AND STRENGTHENING OF PLASTIC MATERIALS 370
7.11 CREEP AND FRACTURE OF POLYMERIC MATERIALS 376
CHAPTER 8 PHASE DIAGRAMS 395
8.1 PHASE DIAGRAMS OF PURE SUBSTANCES 396
8.2 GIBBS PHASE RULE 397
8.3 BINARY ISOMORPHOUS ALLOY SYSTEMS 399
8.4 THE LEVER RULE 402
8.5 NONEQUILIBRIUM SOLIDIFICATION OF ALLOYS 405
8.6 BINARY EUTECTIC ALLOY SYSTEMS 408
8.7 BINARY PERITECTIC ALLOY SYSTEMS 415
8.8 BINARY MONOTECTIC SYSTEMS 421
8.9 INVARIANT REACTIONS 423
8.10 PHASE DIAGRAMS WITH INTERMEDIATE PHASES AND COMPOUNDS 424
8.11 TERNARY PHASE DIAGRAMS 424
CHAPTER 9 ENGINEERING ALLOYS 437
9.1 PRODUCTION OF IRON AND STEEL 438
9.2 THE IRON-IRON CARBIDE PHASE DIAGRAM 441
9.3 HEAT TREATMENT OF PLAIN-CARBON STEELS 450
9.4 LOW-ALLOY STEELS 468
9.5 ALUMINUM ALLOYS 476
9.6 COPPER ALLOYS 493
9.7 STAINLESS STEELS 499
9.8 CAST IRONS 504
9.9 MAGNESIUM,TTTANIUM.AND NICKEL ALLOYS 512
CHAPTER 10 CERAMIC MATERIALS 527
10.1 INTRODUCTION 527
10.2 SIMPLE CERAMIC CRYSTAL STRUCTURES 529
10.3 SILICATE STRUCTURES 543
10.4 PROCESSING OF CERAMICS 548
10.5 TRADITIONAL AND TECHNICAL CERAMICS 555
10.6 ELECTRICAL PROPERTIES OF CERAMICS 559
10.7 MECHANICAL PROPERTIES OF CERAMICS 568
10.8 THERMAL PROPERTIES OF CERAMICS 573
10.9 GLASSES 577
CHAPTER 11 MAGNETIC MATERIALS 597
11.1 MAGNETIC FIELDS AND QUANTITIES 598
11.2 TYPES OF MAGNETISM 602
11.3 EFFECT OFTEMPERAI URE ON FERROMAGNETISM 607
11.4 FERROMAGNETIC DOMAINS 607
11.5 TYPES OF ENERGIES THAT DETERMINE THE STRUCTURE OF FERROMAGNETIC DOMAINS 609
11.6 THE MAGNETIZATION AND DEMAGNETIZATION OF A FERROMAGNETIC METAL 615
11.7 SOFT MAGNETIC MATERIALS 616
11.8 HARD MAGNETIC MATERIALS 621
11.9 FERRITES 629
CHAPTER 12 CORROSION 643
12.1 GENERAL 643
12.2 ELECTROCHEMICAL CORROSION OF METALS 644
12.3 GALVANIC CELLS 648
12.4 CORROSION RATES (KINETICS) 661
12.5 TYPES OF CORROSION 667
12.6 OXIDATION OF METALS 682
12.7 CORROSION CONTROL 686
CHAPTER 13 COMPOSITE MATERIALS 699
13.1 INTRODUCTION 699
13.2 FIBERS FOR REINFORCED-PLASTIC COMPOSITE MATERIALS 701
13.3 FIBER-REINFORCED-PLASTIC COMPOSITE MATERIALS 707
13.4 OPEN-MOLD PROCESSES FOR FIBER-REINFORCED-PLASTIC COMPOSITE MATERIALS 717
13.5 CLOSED-MOLD PROCESSES FOR FIBER-REINFORCED-PLASTIC COMPOSITE MATERIALS 722
13.6 CONCRETE 724
13.7 ASPHALT AND ASPHALT MIXES 734
13.8 WOOD 735
13.9 SANDWICH STRUCTURES 743
Appendix Ⅰ Some Properties of Selected Elements 755
Appendix Ⅱ Ionic Radii of the Elements 757
Appendix Ⅲ Selected Physical Quantities and Their Units 759
Answers to Selected Problems 761
Indes 767