《燃煤烟气汞排放控制 英文版》PDF下载

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  • 作  者:吴江等著
  • 出 版 社:上海:上海交通大学出版社
  • 出版年份:2015
  • ISBN:9787313141101
  • 页数:160 页
图书介绍:汞(Hg)是对环境和人类健康危害最严重的有毒重金属之一。汞从自然和人为来源中释放到大气,其排放控制已经引起了多方面的重视。本书介绍了自然和人为来源的汞污染和工业中的燃煤烟气的汞排放控制,特别是系统地描述了燃煤发电站的汞排放控制。本书对汞排放的控制理论和实验研究进行了论述,包括汞元素是如何被氧化成氧化汞以及烟气成分对汞形态转换过程的影响。本书全面地介绍了汞排放的控制方法,例如:电厂里现有的APCDs(空气污染控制设备)方法、吸附剂喷射法、煤燃烧的添加剂法和光催化法。本书作者系统性地给出了实验室规模、中试规模以及工业应用规模上的吸附剂喷射的实验研究成果,这有助于研究人员和工程师对吸附剂喷射法降低汞排放机理的理解以及应用这些方法在燃煤发电厂进行汞排放的控制。读者可以全面地了解可能的汞排放控制方法以及其中一些方法的工业应用。

1 Mercury and Its Effectson Environment and Human's Health 1

1.1 Mercury Emission Sources 1

1.2 Mercury Speciation and Its Transportation 3

1.3 The Effect of Mercury on Environment and Human's Health 4

References 13

2 The Status of Mercury Emission from Coal Combustion Power Station 19

2.1 Flue Gas Mercury Emission and Its Speciation 20

2.2 The Status of Mercury Emission in the USA 23

2.3 The Status of Mercury Emission in China 24

2.4 The Status of Global Mercury Emission 26

References 29

3 Coal-Fired-Derived Flue Gas Mercury Measurement 31

3.1 Ontario Hydro Method(OHM) 32

3.1.1 Introduction of OHM 32

3.1.2 Procedure and QA/QC of OHM 32

3.2 Semicontinuous Emission Monitor(SCEM) 34

3.2.1 Introduction of SCEM 34

3.2.2 Comparison Between Different SCEM Methods 36

3.3 Appendix K(Sorbent Trap Method) 43

3.4 Comparison Between Different Mercury Emission Measurement Methods 43

3.4.1 Comparison Between SCEM and OHM 43

3.4.2 Comparison Between OHM,SCEM,and Appendix K 47

3.5 The Effects of Mercury Measurements on Mercury Speciation 50

References 52

4 The Influence Factors on Mercury Speciation 55

4.1 The Effect of Halogen on Mercury Speciation 57

4.1.1 The Effect of Chlorine and Chloride on Mercury Speciation 58

4.1.2 The Effect of Other Halogen on Mercury Speciation 61

4.1.3 Addition of Hydrogen Bromide(HBr) 62

4.1.4 Addition of Hydrogen Iodine(HI) 63

4.1.5 Comparison of Impacts on Hg(0)Oxidation by Different Halogen Additives 64

4.2 The Effect of SO2,NOx,and Other Constitutes on Mercury Speciation 68

4.2.1 The Effect of SOx on Mercury Speciation 68

4.2.2 The Effect of NOx on Mercury Speciation 70

4.2.3 The Effect of NO and SO2 on Mercury Oxidation by HCl 71

4.2.4 The Effect of H2O on Mercury Speciation 72

4.2.5 The Effect of Fly Ash on Mercury Speciation 73

References 74

5 Coal-Fired Flue-Gas Mercury Control Technologies 77

5.1 The Co-benefit of Existing Air Pollution Control Devices(APCDs) 79

5.2 Sorbent Development and Its Mercury Emission Removal Efficiency 84

5.2.1 Activated Carbon(AC)and Powdered Activated Carbon(PAC) 85

5.2.2 Modified Powdered Activated Carbon 88

5.2.3 Fly Ash 95

5.2.4 Novel Sorbent 100

5.3 Evaluation of the Effect of Sorbent Injection on Mercury Removal 111

5.4 Additives into the Coal Combustion 125

5.5 Multi-poilution Emission Control Technology 129

5.6 The Developing Trend of Coal-Fired Flue-Gas Mercury Emission Controls 146

5.6.1 Fuel/Raw Material Pretreatment 146

5.6.2 Existing Air Pollution Control Devices(APCDs) 147

5.6.3 Mercury Adsorption 147

5.6.4 Mercury Oxidation 149

References 153

Index 159