Thermodynamics-How much are the real heats of electrode reaction？PDF电子书下载

Chapter 1 On Thermoelectrochemistry 1

1.1 Theory and Application of Thermoelectrochemistry 2

1.2 Some Basic Matters on the Heat Effects at Electrode-Electrolyte Interfaces 26

1.3 Thermoelectrochemistry and Its Application to Metallurgical Research 41

1.4 The Electrochemical Peltier Heat of the Standard Hydrogen Electrode Reaction 50

1.5 Response to"Comment on'The Electrochemical Peltier Heat of the Standard Hydrogen Electrode Reaction'by Zheng Fang et al" 62

1.6 Basic Equations for Thermo-electrochemistry and the Entropy Change of the Standard Hydrogen Electrode Reaction 71

1.7 The Peltier Heat and the Standard Electrode Potential of Ferroferricyanide Couple at 298.15K Determined by Electrochemicalcalorimetry 75

1.8 Determination of the Entropy Changes for Electrode Reaction and Dilute Enthalpy of Some Ions by Thermoelectrochemical Technology 88

References 93

Chapter 2 On Solution Chemistry 99

2.1 A New Model for Predicting Thermodynamic Properties of Ternary Metallic Solution from Binary Components 100

2.2 A Metallic Solution Model with Adjustable Parameter for Describing Ternary Thermodynamic Properties from Its Binary Constituents 110

2.3 A Model Describing the Osmotic Coefficients and the Activities of Water for Electrolyte Solutions 121

2.4 The Mean Activity Coefficients of LaCl3 in Dilute Aqueous Solution at 298.15 K 139

2.5 A Simplified Regular Solution Model for Solubility of Nonmetal(2)in Metal(1)-Metal(3)Alloy Systems 151

2.6 Modeling of Thermodynamic Properties of Multicomponent Electrolyte Solutions 159

2.7 A Simplified Subregular Solution Model Describing the Activites of MgCl2 in Both KCl-MgCl2-LiCl and CaCl2-MgCl2-NaCl Molten Salt Systems 167

2.8 A Model for the Activity Coefficients of Water in Aqueous Solution of HCl-MCln(M=Ni,Cu,Na,and Fe)with Constant Concentration Ratio XHCl/XMCln 173

2.9 A Prediction of the Excess Partial Molar Free Energies of MgCl2 in the KCl-MgCl2-LiCl Molten Salt System Containing MgCl2 below 0.5 from Thermodynamic Properties of Binary Systems 178

References 184

Chapter 3 On Phase Boundaries of Multicomponent System 187

3.1 Complete Integration of Gibbs-Duhem Equation along Phase Boundaries in Multicomponent System 188

3.2 Activities on Phase Boundaries in Multicomponent Systems—A Recursion Formula for Calculation of Activities 192

3.3 An Analogue Margules Equation on Phase Boundaries in Multicomponent Systems 201

References 208

Chapter 4 On Oxygen Potentials of Buffer Gases 209

4.1 Oxygen Potentials and Oxygen-potential Diagrams for Buffer Gas System at Normal Pressure 210

4.2 Effect of Oxygen Contents on Oxygen Potentials of H2O-H2 and H2O-H2-Inerts Gas Mixtures 222

4.3 Oxygen Potentials of CO2,H2O(g)and CO2-CO Gas Mixtures—with Extension of Application of Ellingham Diagram 234

References 248

Chapter 5 On Thermodynamic Properties of Substances 250

5.1 A Study on Thermodynamic Properties in the System MoO2-Mo by Gas Equilibration Method 251

5.2 Equilibria of the System MoO3-MoO2-H2O-H2 and Phase Diagram for the System Mo-O between 400 and 700℃ 262

5.3 Equilibrium between Non-stoichiometric MoO2 and Mo with Application of Sieverts'Law Constant to Smiltens'Integration 270

5.4 A New Molybdenum Oxide Phase 274

5.5 Recovery of Gallium from Coal Fly Ash 279

References 294