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Introduction 1

0.1　Chemistry：A Science for the 21st Century 2

0.2　Scientific Method of Inorganic Chemistry 3

0.3　The Relationship of Inorganic Chemistry and Other Subjects 3

0.4　How do You Study This Course to Get Well? 3

Exercises 3

Chapter 1　The Behaviors of Gas,Liquid and Solution 4

内容提要 4

1.1　The Properties of Gases 5

1.2　The Properties of Liquid 9

1.3　The Properties of Solutions 14

Exercises 22

Chapter 2　Chemical Thermodynamics 23

内容提要 23

2.1　First Law of Thermodynamics 25

2.2　Second Law of Thermodynamics 27

2.3　Third Law of Thermodynamics 28

2.4　Gibbs Free Energy 29

2.5　Hess's Law 30

Exercises 31

Chapter 3　Chemical Dynamics 33

内容提要 33

3.1　The Rates of Chemical Reactions 35

3.2　Transition State(Eyring,1930's) 40

3.3　Catalysis 41

Exercises 42

Chapter 4　The Ionization Equilibria and Theories of Acids ＆ Bases 44

内容提要 44

4.1　Theories of Acids and Bases 46

4.2　Strong and Weak Bases 49

4.3　Strong and Weak Acids 51

4.4　Common Ion Effect and Buffered Solution 54

4.5　The Dissociation of Weak Polyacids and Hydrolysis of Salts 54

Exercises 55

Chapter 5　The Equilibrium of Precipitation and Dissolution 57

内容提要 57

5.1　Solubility Product 58

5.2　Qsp,Ksp and Saturation 58

5.3　Molar Solubilities and Solubility Products 59

5.4　The Common-Ion Effect 60

5.5　How to Separate Ions by Selective Precipitation 60

5.6　The Simultaneous Equilibria Between Precipitations 61

Exercises 62

Chapter 6　Oxidation-Reduction Reactions ＆ Electrochemistry 63

内容提要 63

6.1　Oxidation-Reduction Reactions 64

6.2　Electrode Potential 67

6.3　Electrochemical Cells 70

6.4　The Nernst Equation 72

6.5 Some Application 74

Exercises 74

Chapter 7　The Atomic Structure and the Periodic Properties of the Elements 76

内容提要 76

7.1　Atom Structure 78

7.2　The Spectrum of Atomic Hydrogen and Bohr's Theory 81

7.3　Atomic Orbitals and Electron Configurations 83

7.4　The Periodic Properties of the Elements 89

Exercises 97

Chapter 8　Chemical Bonds and Structures 98

内容提要 98

8.1　Covalent Bonds 102

8.2　Molecular Geometry 106

8.3　Ionic Bond 111

8.4　The Structures of Crystalline Solids 113

8.5　Metallic Bond 114

8.6　Intermolecular Bonding-Van der Waals Forces 115

8.7　Intermolecular Bonding Hydrogen Bond 118

Exercises 121

Chapter 9　The Main-Group Elements 122

内容提要 122

9.1　Introduction 132

9.2　The Chemistry of Hydrogen 134

9.3　The Alkali Metals(Group 1 or Group IA) 135

9.4　The Alkaline Earth Metals(Group 2) 140

9.5　Boron Group(Group 13) 146

9.6　Carbon Group(Group 14) 153

9.7　Nitrogen Group(Group 15) 159

9.8　Chalcogen Group(Group 16) 170

9.9　Halogens Group(Group 17) 177

9.10　The Noble Gases(Group 18) 183

Exercises 187

Chapter 10　The Transition Metal Elements 189

内容提要 189

10.1 Introduction 195

10.2　Group 4(The Titanium Subgroup) 197

10.3　Group 5(The Vanadium Subgroup) 200

10.4　Group 6(The Chromium Subgroup) 203

10.5　Group 7(The Manganese Subgroup) 207

10.6　Group 8(The Iron Subgroup) 210

10.7　Group 9(The Cobalt Subgroup) 217

10.8　Group 10(The Zine Subgroup) 220

10.9　Group 11(The Copper Subgroup) 223

Exercises 228

Chapter 11　The Lanthanides and Actinides 230

内容提要 230

11.1　Definitions 231

11.2　Periodicity 232

11.3　Lanthanides 232

11.4　Actinides 240

11.5　Uranium Chemistry and Nuclear Chemistry 243

Exercises 247

Chapter 12　Introduction of Bio-Inorganic Chemistry 249

内容提要 249

12.1　Introduction 249

12.2　Major Areas of Bio-Inorganic Chemistry 249

12.3　Biomedicine Application 252

Exercises 253

Appendix A：References and Further Reading 254

Appendix B：International System of Units(SI)and Units Conversion 255

Appendix C：Saturation Vapor Pressure over Water for Different Temperatures 257

Appendix D：Dissociation Constant K for Weak Acid and Weak Base 258

Appendix E：AfHΘm,AfGΘm and SΘm for Some Typical Compounds 259

Appendix F：Solubility-Product Constants(Ksp)of Slightly Soluble Ionic Compounds at 298 K 260

Appendix G：Standard Electrode Potentials in Aqueous Solution 261

Appendix H：Standard Heat of Combustion for Typical Organic Compounds 262

Appendix I：Periodic Table of Elements 263