高分子物理 “结构与性能”背后的概念 原书第3版 英文PDF电子书下载

出版说明 1

推荐序 1

Preface（前言） 1

Preface to the First Edition/第1版前言 1

1 Constitution and Architecture of Chains/链的组成与构造 1

2 Single Chain Conformations/单链构象 15

2.1 Rotational Isomeric States/旋转异构态 15

2.2 Helices/螺旋 19

2.3 Coils/线团 22

2.3.1 The Ideal Chain/理想链 26

2.3.2 The Expanded Chain/膨胀链 45

2.4 The Persistent Chain/持续链 55

2.5 The Ising Chain/伊辛链 59

3 Polymer Solutions/聚合物溶液 69

3.1 Dilute and Semidilute Solutions/稀溶液与半稀溶液 70

3.1.1 Osmotic Pressure/渗透压 71

3.2 Screening of Excluded Volume Forces/排除体积力的屏蔽 82

3.3 Polyelectrolyte Solutions/聚电解质溶液 89

3.3.1 Condensation and Screening of Charges/电荷的团聚与屏蔽 89

3.3.2 Chain Stretching， Salt Effects and Interchain Ordering/链伸展、盐效应与链间序 95

3.3.3 Osmotic Pressure/渗透压 100

4 Polymer Blends and Block Copolymers/共混物与嵌段共聚物 105

4.1 The Flory-Huggins Treatment of Polymer Mixtures/聚合物混合物的Flory-Huggins处理方法 106

4. 1. 1 Phase Diagrams： Upper and Lower Miscibili Gap/相图：上临界与下临界混溶间隙 117

4. 2 Phase Separation Mechanisms/相分离机理 122

4. 3 Critical Fluctuations and Spinodal Decomposition/临界涨落与旋节线分解 129

4.3.1 Critical Scattering/临界散射 132

4.3.2 Decomposition Kinetics/分解动力学 143

4.4 Block Copolymer Phases/嵌段共聚物的相结构 151

4.4.1 Layered Structures/层状结构 155

4.4.2 Pretransitional Phenomena/前转变现象 157

5 The Semicrystalline State/半结晶态 165

5.1 Structure Characteristics/结构特征 167

5.1.1 Morphological Elements/基本形态 167

5.1.2 Structure Parameters/结构参数 173

5.2 Kinetics of Crystallization and Melting/结晶与熔融动力学 181

5.3 Laws for the Structure Development/结构变化规律 190

5.3.1 The Multistage Model/多阶段模型 199

5.4 Mechanisms of Secondary Crystallization/二级结晶机理 205

5.4.1 The Insertion Mode/插层模式 208

5.4.2 Surface Crystallization and Melting/表面结晶与熔融 212

5.5 Crystallization from Oriented Melts/取向熔体结晶 216

6 Mechanical and Dielectric Response/力学与介电响应 223

6.1 Response Functions/响应函数 224

6.1.1 Viscoelasticity/粘弹性 224

6.1.2 Orientational Polarization/取向极化 228

6.1.3 General Relationships/通用公式 229

6.2 Relaxatory Modes/松弛模式 236

6.2.1 Single-Time Relaxation Process/单时间松弛过程 237

6.2.2 Retardation and Relaxation Time Spectra/推迟与松弛时间 242

6.3 Specific Relaxation Processes and Flow Behavior/具体松弛过程与流动行为 245

6.3.1 Local Processes/局部过程 246

6.3.2 Glass-Rubber Transition and Melt Flow/玻璃-橡胶转变与熔体流动 250

6.3.3 The Glass Transition Temperature/玻璃化转变温度 269

6.3.4 Relaxation in Partially Crystalline Systems/半晶体系中的松弛 277

7 Conjugated Polymers/共轭聚合物 287

7.1 Electrooptic Activity/光电活性 289

7.1.1 Excitons and Free Charges/激发与自由电荷 289

7.1.2 Electroluminescence/电发光 297

7.2 Effects of Doping/掺杂效应 302

7.2.1 Electrical Conductivity/电导率 302

7.2.2 Magnetism and Reflectivity/磁性与反射率 306

8 Microscopic Dynamics/微观运动学 313

8.1 The Fluctuation§Dissipation Theorem/涨落-耗散原理 313

8.2 The Rouse Model/Rouse模型 317

8.2.1 Stress Relaxation/应力松弛 325

8.2. 2 The Dielectric Normal Mode/介电基准模式 330

8.3 Entanglement Effects in Polymer Melts/聚合物熔体中的缠结效应 333

8.3.1 The Reptation Model/爬行模型 338

8.4 Solution Viscosities/溶液粘度 343

8.4.1 Neutral Polymers： Hydrodynamic Interaction/中性聚合物：流体力学作用 344

8.4.2 Polyelectrolytes ： Coulomb Interaction/聚电解质：静电作用 352

9 Non-Linear Mechanics/非线性力学 357

9.1 Rubber Elasticity/橡胶弹性 361

9.1. 1 The Fixed Junction Model of Ideal Rubbers/理想橡胶的固定结点模型 364

9.1. 2 The Cauchy Strain Tensor/ Cauchy应变张量 371

9.1.3 Finger's Constitutive Equation/ Finger本构方程 376

9.2 Swelling of Neutral and Electrolytic Gels/中性与电解质凝胶的溶胀 384

9.3 Non-Newtonian Melt Flow/非牛顿熔体的流动 390

9.3. 1 Rheological Material Functions/流变材料函数 391

9.3.2 The Lodge Liquid/ Lodge液体 398

9.3. 3 The Stress-Optical Rule/应力-光学规则 404

10 Deformation，Yielding and Fracture/形变、屈服与断裂 415

10.1 Shear Deformation in Semicrystalline Polymers/半晶聚合物中的剪切形变 418

10.1.1 Critical Strains/临界应变 418

10.1.2 Constituents of the Drawing Stress/拉伸应力的成分 426

10.1.3 The Mechanics of Neck Formation/细颈形成机理 429

10.1.4 Fibrillar State of Order/纤维化有序态 435

10.2 Crazing/银纹 444

10.3 Brittle Fracture/脆性断裂 450

10.3.1 Linear Fracture Mechanics/线性断裂力学 453

10.3.2 The Slow Mode of Crack Growth/裂缝生长的缓慢模式 455

A Scattering Experiments/散射实验 463

A.1 Fundamentals/基本概念 463

A.1.1 Basic Equations/基本方程 464

A.1. 2 Time-Resolved Scattering Experiments/时间分解的散射实验 468

A.2 Absolute Intensities/绝对强度 471

A.3 Low Angle Scattering Properties/小角散射性质 474

A.3.1 Guinier's Law/ Guinier公式 474

A.3.2 Forward Scattering/前散射 476

A.4 Special Polymer Systems/特种聚合物体系 477

A.4.1 Binary Mixtures and Block Copolymers/二元混合物与嵌段共聚物 477

A.4.2 Two-Phase Layer Systems/两相层状体系 484

B Glossary of Symbols/术语与符号 493

C Bibliography/参考书目 501

References/参考文献 505

Index/索引 505